Changes in the adsorbate dipole layer with changing d-filling of the metal (II) (Co, Ni, Cu) phthalocyanines on Au(111).
نویسندگان
چکیده
In combined photoemission and inverse photoemission spectroscopy studies, we observe changes in the metal phthalocyanine molecular orbital offsets with respect to the conducting gold substrate Fermi level, with the changing d-electron filling of the metal (II) (Co, Ni, Cu) phthalocyanines. The implication is that the interfacial dipole layer depends upon the choice of metal (Co, Ni, Cu) centers within the metal (II) phthalocyanines adsorbed on Au(111).
منابع مشابه
Activity of Cu-Co-M (M= Ce, Ni, Au, Mg) catalysts prepared by coprecipitation method, calcined at high temperature for CO oxidation
The present study deals with analysis of the activity of catalysts prepared by addition of different metals to Copper and Cobalt based catalysts for CO oxidation and the variation in activity caused by changes in composition. A series of catalysts were prepared with Cu:Co molar ratio 1:4 and a third metal (M= Ce, Ni, Au, Mg) was added in three different quantities. Compositions were prepared by...
متن کاملActivity of Cu-Co-M (M= Ce, Ni, Au, Mg) catalysts prepared by coprecipitation method, calcined at high temperature for CO oxidation
The present study deals with analysis of the activity of catalysts prepared by addition of different metals to Copper and Cobalt based catalysts for CO oxidation and the variation in activity caused by changes in composition. A series of catalysts were prepared with Cu:Co molar ratio 1:4 and a third metal (M= Ce, Ni, Au, Mg) was added in three different quantities. Compositions were prepared by...
متن کاملThe interface structure of n-alkylthiolate self-assembled monolayers on coinage metal surfaces.
The current state of understanding of the structure of the metal/thiolate interface of n-alkylthiolate 'self-assembled monolayers' (SAMs) on Cu(111), Ag(111) and Au(111) is reviewed. On Cu(111) and Ag(111) there is now clear evidence that adsorbate-induced reconstruction of the outermost metal layer occurs to a less atomically-dense structure, with the S head-group atom bonded to four-fold and ...
متن کاملBinding configuration, electronic structure, and magnetic properties of metal phthalocyanines on a Au(111) surface studied with ab initio calculations
Binding configurations, interface electronic structures, and magnetic properties of 3d transition-metal phthalocyanine (MPc, where M = Mn, Fe, Co, Ni, Cu or Zn) molecular systems on a Au(111) substrate are systematically investigated with first-principles density functional theory calculations using the Perdew-Wang (PW91) exchange-correlation functional. We also calculate the corresponding prop...
متن کاملSelective Sorption of Heavy Metal Ions from Aqueous Solutions Using m-Cresol Based Chelating Resin and Its Analytical Applications
Salicylic acid-Formaldehyde-m-Cresol (SFM) terpolymer had been synthesized in DMF media by conventional method. The resulting resin had been characterized by FTIR spectra, elemental and thermogravimetric analyses. The morphology of SFM resin had been studied by SEM and Optical photograph. Various parameters like rate of equilibration, effect of pH on ion exchange capacity and effect of conc...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Journal of physics. Condensed matter : an Institute of Physics journal
دوره 21 5 شماره
صفحات -
تاریخ انتشار 2009